1ª Divisão Copa do Rei
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| Real Madrid | Barcelona | A. Madrid | A.Bilbao | Valencia | D. La Coruña |
| (Madrid) | (Barcelona) | (Madrid) | (Bilbao) | (Valencia) | ( La Coruña) |
| 31 | 21 | 09 | 08 | 06 | 01 |
| Campeonato Espanhol - 1ª Divisão | ||
| Ano | Campeão | Vice |
| 2010/2011 | Barcelona | Real Madrid |
| 2009/2010 | Barcelona | Real Madrid |
| 2008/2009 | Barcelona | Real Madrid |
| 2007/2008 | Real Madrid | Villareal CF |
| 2006/2007 | Real Madrid | Barcelona |
| 2005/2006 | Barcelona | Real Madrid |
| 2004/2005 | Barcelona | Real Madrid |
| 2003/2004 | Valencia | Barcelona |
| 2002/2003 | Real Madrid | Real Sociedad |
| 2001/2002 | Valencia | Deportivo La Coruña |
| 2000/2001 | Real Madrid | Deportivo La Coruña |
| 1999/2000 | Deportivo La Coruña | Barcelona |
| 1998/1999 | Barcelona | Real Madrid |
| 1997/1998 | Barcelona | Real Madrid |
| 1996/1997 | Real Madrid | Barcelona |
| 1995/1996 | Atletico de Madrid | Valencia |
| 1994/1995 | Real Madrid | Deportivo La Coruña |
| 1993/1994 | Barcelona | Deportivo La Coruña |
| 1992/1993 | Barcelona | Real Madrid |
| 1991/1992 | Barcelona | Real Madrid |
| 1990/1991 | Barcelona | Atletico de Madrid |
| 1989/1990 | Real Madrid | Valencia |
| 1988/1989 | Real Madrid | Barcelona |
| 1987/1988 | Real Madrid | Real Sociedad |
| 1986/1987 | Real Madrid | Barcelona |
| 1985/1986 | Real Madrid | Barcelona |
| 1984/1985 | Barcelona | Atletico de Madrid |
| 1983/1984 | Athletic Bilbao | Real Madrid |
| 1982/1983 | Athletic Bilbao | Real Madrid |
| 1981/1982 | Real Sociedad | Barcelona |
| 1980/1981 | Real Sociedad | Real Madrid |
| 1979/1980 | Real Madrid | Real Sociedad |
| 1978/1979 | Real Madrid | Sporting de Gijón |
| 1977/1978 | Real Madrid | Barcelona |
| 1976/1977 | Atletico de Madrid | Barcelona |
| 1975/1976 | Real Madrid | Barcelona |
| 1974/1975 | Real Madrid | Real Zaragoza |
| 1973/1974 | Barcelona | Atletico de Madrid |
| 1972/1973 | Atletico de Madrid | Barcelona |
| 1971/1972 | Real Madrid | Valencia |
| 1970/1971 | Valencia | Barcelona |
| 1969/1970 | Atletico de Madrid | Athletic Bilbao |
| 1968/1969 | Real Madrid | UD Las Palmas |
| 1967/1968 | Real Madrid | Barcelona |
| 1966/1967 | Real Madrid | Barcelona |
| 1965/1966 | Atletico de Madrid | Real Madrid |
| 1964/1965 | Real Madrid | Atletico de Madrid |
| 1963/1964 | Real Madrid | Barcelona |
| 1962/1963 | Real Madrid | Atletico de Madrid |
| 1961/1962 | Real Madrid | Barcelona |
| 1960/1961 | Real Madrid | Atletico de Madrid |
| 1959/1960 | Barcelona | Real Madrid |
| 1958/1959 | Barcelona | Real Madrid |
| 1957/1958 | Real Madrid | Atletico de Madrid |
| 1956/1957 | Real Madrid | Sevilla |
| 1955/1956 | Athletic Bilbao | Barcelona |
| 1954/1955 | Real Madrid | Barcelona |
| 1953/1954 | Real Madrid | Barcelona |
| 1952/1953 | Barcelona | Valencia |
| 1951/1952 | Barcelona | Athletic Bilbao |
| 1950/1951 | Atletico de Madrid | Sevilla |
| 1949/1950 | Atletico de Madrid | Deportivo La Coruña |
| 1948/1949 | Barcelona | Valencia |
| 1947/1948 | Barcelona | Valencia |
| 1946/1947 | Valencia | Athletic Bilbao |
| 1945/1946 | Sevilla | Barcelona |
| 1944/1945 | Barcelona | Real Madrid |
| 1943/1944 | Valencia | Atletico de Madrid |
| 1942/1943 | Athletic Bilbao | Sevilla |
| 1941/1942 | Valencia | Real Madrid |
| 1940/1941 | Atlético de Madrid | Athletic Bilbao |
| 1939/1940 | Atlético de Madrid | Sevilla |
| 1937 a 1939 | Não houve | - |
| 1935/1936 | Athletic Bilbao | Real Madrid |
| 1934/1935 | Real Betis Sevilla | Real Madrid |
| 1933/1934 | Athletic Bilbao | Real Madrid |
| 1932/1933 | Real Madrid | Athletic Bilbao |
| 1931/1932 | Real Madrid | Athletic Bilbao |
| 1930/1931 | Athletic Bilbao | Real RC Santander |
| 1929/1930 | Athletic Bilbao | Barcelona |
| 1928/1929 | Barcelona | Real Madrid |
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Entre os anos de 1937 a 1939 não houve disputa do campeonato nacional devido a segunda grande guerra mundial.
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